Search results for "Oxygen isotope ratio cycle"
showing 10 items of 10 documents
Oxygen isotope compositions of phosphate from arvicoline teeth and Quaternary climatic changes, Gigny, French Jura
2004
Oxygen isotope compositions of biogenic phosphates from mammals are widely used as proxies of the isotopic compositions of meteoric waters that are roughly linearly related to the air temperature at high- and mid-latitudes. An oxygen isotope fractionation equation was determined by using present-day European arvicoline (rodents) tooth phosphate: δ18Op = 20.98(±0.59) + 0.572(±0.065) δ18Ow. This fractionation equation was applied to the Late Pleistocene karstic sequence of Gigny, French Jura. Comparison between the oxygen isotope compositions of arvicoline tooth phosphate and Greenland ice core records suggests to reconsider the previously established hypothetical chronology of the sequence. …
Rhinocerotid tooth enamel 18O/16O variability between 23 and 12 Ma in southwestern France.
2006
Abstract The relationship between the oxygen isotope ratio of mammal tooth enamel and that of drinking water was used to reconstruct changes in the Miocene oxygen isotope ratio of rainfall (meteoric water δ 18 O MW ). These, in turn, are related to climatic parameters (temperature, precipitation and evaporation rate). δ 18 O values of rhinocerotid teeth from the Aquitaine Basin (southwestern France) suggest a significant climatic change between 17 and 12 Ma, characterized by cooling together with precipitation increase, in agreement with other terrestrial and oceanic records. To cite this article: I. Bentaleb et al., C. R. Geoscience 338 (2006).
Revised phosphate-water fractionation equation reassessing paleotemperatures derived from biogenic apatite.
2010
8 pages; International audience; Oxygen isotopes of biogenic apatite have been widely used to reassess anomalous temperatures inferred from oxygen isotope ratios of ancient biogenic calcite, more prone to diagenetic alteration. However, recent studies have highlighted that oxygen isotope ratios of biogenic apatite differ dependent on used analytical techniques. This questions the applicability of the phosphate–water fractionation equations established over 25 years ago using earlier analytical techniques to more recently acquired data. In this work we present a new phosphate–water oxygen isotope fractionation equation based on oxygen isotopes determined on fish raised in aquariums at contro…
Characterization of Hydrothermal Processing Influence on Strontium Substituted Apatite by Investigating Stable Oxygen Isotope Ratio and Antibacterial…
2018
Synthetic hydroxyapatite (HAp) has weak antibacterial and mechanical properties. The antibacterial activity of HAp can be enhanced by strontium cation substitution and incorporation of peroxide ion via hydrothermal processing at 100 °C and 150 °C temperature using 50% H2O2 solution. The starting reagents and products of HAp processing were analyzed by thermal conversion elemental analyser – isotopic ratio mass spectrometer in order to determine the δ18O values. Using different host materials it could be possible to determine differences of δ18O values between untreated and hydrothermally treated HAp samples. The enhanced antibacterial properties of processed HAp samples were investigated us…
Multi-isotopic and trace element evidence against different formation pathways for oyster microstructures
2021
Geochimica et cosmochimica acta 308, 326-352 (2021). doi:10.1016/j.gca.2021.06.012
Climatic dependence of stable carbon and oxygen isotope signals recorded in speleothems: From soil water to speleothem calcite
2011
Abstract Understanding the relationship between stable isotope signals recorded in speleothems (δ 13 C and δ 18 O) and the isotopic composition of the carbonate species in the soil water is of great importance for their interpretation in terms of past climate variability. Here the evolution of the carbon isotope composition of soil water on its way down to the cave during dissolution of limestone is studied for both closed and open-closed conditions with respect to CO 2 . The water entering the cave flows as a thin film towards the drip site. CO 2 degasses from this film within approx. 10 s by molecular diffusion. Subsequently, chemical and isotopic equilibrium is established on a time scal…
Modelling the δ18O value of cave drip water and speleothem calcite
2010
Abstract Stable isotope signals recorded in speleothems have provided important insights about past climate variability in recent years. Quantitative reconstruction of mean annual temperature and the amount of precipitation, however, remains difficult because the stable isotope signals are influenced by various processes. Here we present a drip water model, which shows how these climate parameters affect the oxygen isotope signal of cave drip water. In the model the dependence of the δ 18 O value of drip water on mean annual temperature is established by correlation to the amount of winter precipitation and winter temperature. Application of the model to two caves in western Germany reveals…
Stable isotope fractionation in speleothems: Laboratory experiments
2010
Abstract In recent years, stalagmites have become important archives for paleoclimate. Several studies applying carbon and oxygen isotopes of stalagmites show a simultaneous increase of δ 13 C and δ 18 O along individual growth layers, which is interpreted as being indicative of isotope fractionation under disequilibrium conditions. In order to obtain robust paleoclimatic information from calcite precipitated under these non-equilibrium conditions it is important to improve the quantitative understanding of the corresponding isotope fractionation processes. Here we present laboratory experiments simulating calcite precipitation under cave-analogue conditions. The major focus was the investi…
Contrasting shell growth strategies in two Mediterranean bivalves revealed by oxygen-isotope ratio geochemistry: The case of Pecten jacobaeus and Gly…
2019
International audience; High-resolution stable-isotope ratio data (delta O-18, delta O-18) were used to study growth strategies of two bivalve species, Pecten jacobaeus (calcitic shell) and Glycymeris pilosa (aragonitic shell) from the North Adriatic Sea. The principal objectives of this study were to identify the period of the year when the growth line is formed in the shell of two target species, to identify the main growing season of these two species, to identify the environmental drivers of shell growth, and to evaluate the potential applicability of delta O-18 and delta O-18 values for the reconstruction of environmental variability. Samples were collected from the North Adriatic Sea …
Stable carbon and oxygen isotope fractionation in bivalve (Placopecten magellanicus) larval aragonite
2008
Abstract The relationship between stable isotope composition (δ13C and δ18O) in seawater and in larval shell aragonite of the sea scallop, Placopecten magellanicus, was investigated in a controlled experiment to determine whether isotopes in larval shell aragonite can be used as a reliable proxy for environmental conditions. The linear relationship between δ13CDIC and δ13Caragonite (r2 = 0.97, p δ 13 C DIC = 1.15 ( ± 0.05 ) ∗ δ 13 C aragonite - 0.85 ( ± 0.04 ) The relationship between δ13CDIC and δ13Caragonite described for P. magellanicus resulted in larval shell aragonite that was depleted on average by 1.82‰ (SD = 0.22‰, range = 1.1–2.1‰) from predicted equilibrium values based on the r…